Marination

Not just a matter of good taste

Marination is a good idea for many reasons - but only under the right conditions. Many advocate it as vital to real taste and others disagree or cannot really be bothered, but few really understand the science behind their reasoning. It acts as a form of pre-digestion: protein-digesting enzymes from plants, such as papaya, fig and pineapple break down muscle and connective tissue in meat and acids, such as vitamin C (lemon juice/orange juice) and vinegars emulate the natural action of lactic acid naturally produced by a living body to break down the proteins for use.
Marination can also be attractive by introducing colour and flavour to the areas in which it comes into contact and in those layers near the surface of the tissue.
It is also a useful combatant of harmful bacteria and moulds, its usually acid nature inhibiting their growth, and when a antibacterial spice, such as turmeric, is used in the marinade, this is reinforced.
With a piece of chicken accumulating anything up to 10,000 bacteria per square centimetre by the time it reaches the supermarkets - even under strictly controlled conditions - this is very comforting.
Studies carried out at the Lawrence Livermore National Laboratory in California, indicate that chicken marinated before grilling contains fewer carcinogens, the substances that may produce cancer in living tissues. Dr Mark Knize and his team marinated chicken breast in olive oil, brown sugar, cider vinegar, lemon juice, garlic, salt and mustard. After cooking it for 20 minutes, they found that it had one-tenth the usual level of heterocyclic amines or less.
Quite a powerful weapon in the cook's armoury, one might say. However, as with all weapons, it is a two edged sword. Marination is a chemical reaction and needs the physical contact of marinade and meat tissue. This takes place at the surface. The centre of the meat is still subject to the natural forms of decomposition. Lactic acid builds up and breaks down the protein, naturally tenderising the meat.
The fat tissue within the meat is no longer supplied with white blood cells and antioxidants, so becomes infected and quickly rancid and those meats which are high in unsaturated fats - fish, poultry, pork, lamb and veal are those which spoil the quickest. This is why marination should be under refrigeration, and for a matter of hours rather than days, to allow flavours to permeate - over-marination just leads to mushy tissue surrounding microbe rich centres.
Scientists have found that the optimum temperature for tenderisers to work well is between 60ºC - 79ºC and are deactivated at boiling point - (100ºC). So the main tenderising action probably acts upon the muscle tissue in the early stages of the actual cooking.
Whatever the pitfalls of modern marination, it is a vast improvement on the methods used up until the end of the last century. Beef joints were hung in storage until the outsides were literally rotten.
The French called this process mortification - but, at the stage of putrefaction they preferred, whose death they were referring to is now lost in the mists of time.